This is a figure from the 2007 IPCC Assessment Report 4 on atmospheric concentrations of carbon dioxide, methane and nitrous oxide over the last 10,000 years (large panels) and since 1750 (inset panels).

This video segment from 'Earth: The Operators' Manual' explores how we know that today's increased levels of CO2 are caused by humans burning fossil fuels and not by some natural process, such as volcanic out-gassing. Climate scientist Richard Alley provides a detailed step-by-step explanation that examines the physics and chemistry of different "flavors," or isotopes, of carbon in Earth's atmosphere.